Copper-catalysed perarylation of cyclopentadiene: synthesis of hexaarylcyclopentadienes

Gisbert, Yohan; Simón Marqués, Pablo; Baccini, Caterina; Abid, Seifallah; Saffon-Merceron, Nathalie; Rapenne, Gwénaël; Kammerer, Claire

doi:10.1039/d4sc02458c

Chem. Sci.

2024

DOI: 10.1039/d4sc02458c

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Copper-catalysed perarylation of cyclopentadiene: synthesis of hexaarylcyclopentadienes

Yohan Gisbert,

Pablo Simón Marqués,

Caterina Baccini

et al.

Abstract: While hexaphenylsilacyclopentadiene (hexaphenylsilole) is viewed as an archetypal Aggregation-Induced Emission (AIE) luminogen, its isostructural hydrocarbon surrogate hexaphenylcyclopentadiene has strikingly never been investigated in this context, most probably due to a...

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Catalytic haloallylation/Zr-mediated dienyne cyclization/isomerization sequence for tailored cyclopentadiene substitution

Gobin,

Nikšić-Franjić,

Topolovčan

2025

Org. Chem. Front.

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Catalytic haloallylation/Zr-mediated dienyne cyclization/isomerization sequence for tailored cyclopentadiene substitution

Gobin,

Nikšić-Franjić,

Topolovčan

2025

Org. Chem. Front.

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Copper-catalysed perarylation of cyclopentadiene: synthesis of hexaarylcyclopentadienes

Abstract: While hexaphenylsilacyclopentadiene (hexaphenylsilole) is viewed as an archetypal Aggregation-Induced Emission (AIE) luminogen, its isostructural hydrocarbon surrogate hexaphenylcyclopentadiene has strikingly never been investigated in this context, most probably due to a...

Cited by 1 publication

References 82 publications

Catalytic haloallylation/Zr-mediated dienyne cyclization/isomerization sequence for tailored cyclopentadiene substitution

Catalytic haloallylation/Zr-mediated dienyne cyclization/isomerization sequence for tailored cyclopentadiene substitution

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