2024
DOI: 10.1002/adsc.202301185
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Copper‐Catalyzed Diazidation of Allenes: Access to 3‐(Azidomethyl)‐2H‐Azirines

Shen‐Yuan Zhang,
Li‐Yan Hu,
Yang Li
et al.

Abstract: A class of 3‐(azidomethyl)‐2H‐azirine has been obtained through a copper‐catalyzed diazidation of allenes and a subsequent azirination involving vinyl azides. A variety of functional groups in the allenes are well tolerated, providing a series of 3‐(azidomethyl)‐2H‐azirine motifs in 51%‐93% yields (26 examples).

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