Copper-containing POM-based hybrid P2Mo22V4Cu4 nanocluster as heterogeneous catalyst for the light-driven hydroxylation of benzene to phenol

Chen, Qun; Jiao, Cheng-Yang; Xu, Hu; Li, Si-Man; Yang, Jian-Bo; Mei, Hua; Xu, Yan

doi:10.1039/d3dt02812g

Dalton Trans.

2024

DOI: 10.1039/d3dt02812g

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Copper-containing POM-based hybrid P2Mo22V4Cu4 nanocluster as heterogeneous catalyst for the light-driven hydroxylation of benzene to phenol

Qun Chen,

Cheng-Yang Jiao,

Hu Xu

et al.

Abstract: A polyoxometalate-based hybrid material was successfully synthesized. It showed good catalytic activity in the reaction of photocatalytic conversion of benzene to phenol, and the mechanism of photocatalytic production of phenol was explored.

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Cited by 2 publications

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Selective hydroxylation of benzene via enhanced generation and utilization of hydroxyl radicals with CuZnSbO photocatalyst

Gonfa,

Shen,

Chen

et al. 2025

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Selective hydroxylation of benzene via enhanced generation and utilization of hydroxyl radicals with CuZnSbO photocatalyst

Gonfa,

Shen,

Chen

et al. 2025

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Catalytic Epimerization of Glucose to Mannose

Wan,

Chu,

Wang

et al. 2024

ACS Sustainable Chem. Eng.

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Conversion of largely abundant glucose to other commercially important sugars has attracted worldwide attention from both academia and industry. As one of the most important commercialized saccharides, mannose has broad application in the food, cosmetic, and pharmaceutical industries. While mannose is traditionally produced from oceanic biomass using the precipitation technique, recent studies have confirmed that it can also be obtained through catalytic epimerization glucose. Among different promising candidates, Mo-and Sn-based nanomaterials have been showing remarkable performances in catalytic activity. Nevertheless, there still remain several technological obstacles hindering practical applications. Those flaws include low selectivity and poor stability as well as restricted pH operating conditions. In this Perspective, the most updated research advances on catalyst design and the reaction mechanisms for epimerization of glucose will be systematically summarized and critically discussed. The challenges and outlooks will be presented to provide insights for process development for producing commercially valuable saccharides in future biorefineries.

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Copper-containing POM-based hybrid P2Mo22V4Cu4 nanocluster as heterogeneous catalyst for the light-driven hydroxylation of benzene to phenol

Abstract: A polyoxometalate-based hybrid material was successfully synthesized. It showed good catalytic activity in the reaction of photocatalytic conversion of benzene to phenol, and the mechanism of photocatalytic production of phenol was explored.

Cited by 2 publications

References 42 publications

Selective hydroxylation of benzene via enhanced generation and utilization of hydroxyl radicals with CuZnSbO photocatalyst

Selective hydroxylation of benzene via enhanced generation and utilization of hydroxyl radicals with CuZnSbO photocatalyst

Catalytic Epimerization of Glucose to Mannose

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