“…Color centers can be created as Cu 2+ ions can give blue glass; however, if a majority of copper ions exist as Cu + rather than Cu 2+ , the glass will appear green. 31 The hopping mechanism involves the hopping of electrons between valences and being trapped by positive-charged holes as electrons of lower valence (Cu + ) move into higher valences (Cu 2+ ) and combine with optical phonons. 32 Cu + exhibits broad bands in optical studies due to the coupling of s-electrons and phonons besides the s → d transition.…”
“…Color centers can be created as Cu 2+ ions can give blue glass; however, if a majority of copper ions exist as Cu + rather than Cu 2+ , the glass will appear green. 31 The hopping mechanism involves the hopping of electrons between valences and being trapped by positive-charged holes as electrons of lower valence (Cu + ) move into higher valences (Cu 2+ ) and combine with optical phonons. 32 Cu + exhibits broad bands in optical studies due to the coupling of s-electrons and phonons besides the s → d transition.…”
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