Copper(II) and (η⁵-Cp*)rhodium(III) complexes of some imidazole and pyridine containing ligands

Abstract

4.1.3. Inhibition of ROS production ……...…………………………………………………..45 4.2. Peptide-based chemical models for lytic polysaccharide monooxigenases ……….………..48 4.2.1. Equilibrium, solution structural and electrochemical studies…………………………..48 4.2.2. Kinetic studies …………………………………………………………………………59 4.2.3. Interaction of dimer complexes with hydrogen peroxide……………………………....63 4.2.4. Mechanistic considerations……………………………………………………………..67 4.3. The interaction of half-sandwich (η 5 -Cp*)Rh(III) cation with histidine containing peptides and their ternary species with (N,N) bidentate ligands…………………………………….…….70 4.3.1 Interaction of (η 5 -Cp*)Rh(III) with some imidazole derivatives and synthetic histidine containing peptides .