Copper Promoted Synthesis of Tetraalkylgermanes from Germanium Electrophiles and Alkyl Bromides<sup>※</sup>

Xu, Qing-Hao; Wei, Li-Pu; Zhang, Zhen; Xiao, Bin

doi:10.6023/a21120608

Acta Chimica Sinica

2022

DOI: 10.6023/a21120608

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Copper Promoted Synthesis of Tetraalkylgermanes from Germanium Electrophiles and Alkyl Bromides^※

Qing-Hao Xu¹,

Li-Pu Wei²,

Zhen Zhang³

et al.

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Cited by 3 publications

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Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives

Tu,

Huang

2024

Adv Synth Catal

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Germanium (Ge), a congener of carbon, possesses unique properties that hold extensive potential for applications across multiple domains. Recent years have seen significant progress in the development of carbon‐germanium bond formation strategies, particularly those for more challenging C(sp3)‐Ge bonds. This review systematically summarizes the recent advances in C(sp3)‐Ge bond forming methodologies, with particular emphasis on (1) the versatility of transition‐metals, including iron, nickel, copper, rhodium and palladium, as catalysts in broadening reaction scope and controlling selectivity; (2) the powerfulness of organic photocatalysis in achieving mild and selective bond formation, and (3) the sustainability of catalytic electrosynthesis in facilitating chemical oxidant‐/reductant‐free conversions. Additionally, examples of (4) non‐catalytic strategies are also discussed. The representative scopes, as well as mechanistic proposals, of these protocols are highlighted. Through an overview on the current state of research, this review aims to offer insights into the catalytic construction of C(sp3)‐Ge bonds, and provide perspectives on future research directions to address the current challenges.

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Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives

Tu,

Huang

2024

Adv Synth Catal

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Organogermanium(iv) compounds in photo-induced radical reactions

Xiao

2022

Org. Chem. Front.

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Advances in the Synthesis of Organogermaniums Based on the Addition Reactions of Alkenes and Alkynes

Lv,

Luo,

2024

Chinese Journal of Organic Chemistry

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Copper Promoted Synthesis of Tetraalkylgermanes from Germanium Electrophiles and Alkyl Bromides^※

Cited by 3 publications

References 24 publications

Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives

Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives

Organogermanium(iv) compounds in photo-induced radical reactions

Advances in the Synthesis of Organogermaniums Based on the Addition Reactions of Alkenes and Alkynes

Contact Info

Product

Resources

About

Copper Promoted Synthesis of Tetraalkylgermanes from Germanium Electrophiles and Alkyl Bromides※

Cited by 3 publications

References 24 publications

Catalytic Construction of C(sp3)−Ge Bonds: Recent Advances and Future Perspectives

Catalytic Construction of C(sp3)−Ge Bonds: Recent Advances and Future Perspectives

Organogermanium(iv) compounds in photo-induced radical reactions

Advances in the Synthesis of Organogermaniums Based on the Addition Reactions of Alkenes and Alkynes

Contact Info

Product

Resources

About

Copper Promoted Synthesis of Tetraalkylgermanes from Germanium Electrophiles and Alkyl Bromides^※

Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives

Catalytic Construction of C(sp³)−Ge Bonds: Recent Advances and Future Perspectives