Copper(I) and copper(II) compounds of a dinucleating, octadentate tetrakisbenzimidazole ligand. Crystal and molecular structures of three dihalogeno{1,8-bis[bis(1′-methylbenzimidazol-2′-ylmethyl)amino]-3,6-dioxaoctane}dicopper(II) bis(anion) compounds (halogen = F, Cl, or Br; anion = BF₄, CF₃SO₃, or Cl)

The `super acid' BF3H2O stabilized by 1,4-dioxane: new preparative aspects and the crystal structure of BF3H2O·C4H8O2

“…A search of the Cambridge Structural Database (CSD; Version 5.40, November 2018 update; Groom et al, 2016) for the BF 3 H 2 O moiety yielded six structures: the crown ether adducts 18-crown-6 monoaquatrifluoridoboron toluene semisolvate (CSD refcode SIXFOU; Bott et al 1991), 18-crown-6 bis(monoaquatrifluoridoboron) dihydrate (LEKYIJ; Feinberg et al 1993, Simonov et al, 1995 and dicyclohexano-18-crown-6 bis(monoaquatrifluoridoboron) (NIYGAD; Fonar et al, 1997); the phosphane oxide adduct monoaquatrifluoridoboron bis(triphenylphosphane oxide) (XATWAR; Chekhlov, 2005); two transition-metal coordination compounds [CIGVUJ10 (Van Rijn et al, 1987) and UKAJIA (Orain et al, 2010)], containing cocrystallized monoaquatrifluoridoboron moieties. As mentioned above, in addition to these reports on compounds having organic components, there is the report of Mootz & Steffen (1981b) on the inorganic parent compound BF 3 H 2 O and there are two reports on the dihydrate BF 3 H 2 OÁH 2 O (Mootz & Steffen, 1981c;Bang & Carpenter, 1964).…”

Dioxygen Activation Using Schiff Base Macrocyclic Dinuclear Copper( I ) Complexes: Structurally Characterized Dioxygen Reaction Products

“…Cu I complexes of the macrocycles 3aϪd were obtained by an addition of in situ generated Cu I perchlorate [38] or Cu I triflate to the ligand solution in dichloromethane (Scheme 2).…”

Complexes of zinc(II) with 1,2-disubstituted benzimidazoles

“…16 The resonance signal due to the -CH 2carbon is observed around 47. [16][17][18][19][20] Thermogravimetric analysis data of ZnX 2 L n .yH 2 O complexes are compiled in Table 2. The complexes show loss of water of hydration as noted from TGA curves.…”