Starter fertilizers containing phosphorus are often applied when planting corn (Zea mays L.) in the Delmarva Region. Recently, a new fertilizer additive called AVAIL (Specialty Fertilizer Products LLC, Leawood, KS) has been promoted in this region as a product that will increase the plant availability of P fertilizers by reducing P adsorption by iron and aluminum minerals. There have been, however, no reported studies in corn that demonstrate that AVAIL increases fertilizer P availability. The objective of this study was to evaluate the value of adding AVAIL to starter fertilizers containing P when growing corn. Early growth of corn was increased by starter fertilizer at all site years; however, AVAIL had no effect on early growth. Grain yields were increased by adding P in the starter fertilizer at only two of the eight site‐years, but AVAIL and no effect on grain yields at any of the site‐years. Overall, our results suggest that AVAIL had no effect on crop uptake or response to P.