We study the worldsheet scattering theory of the η deformation of the AdS5 × S5 superstring corresponding to the purely fermionic Dynkin diagram. This theory is a Weyl-invariant integrable deformation of the AdS5 × S5 superstring, with trigonometric quantum-deformed symmetry. We compute the two-body worldsheet S matrix of this string in the light-cone gauge at tree level to quadratic order in fermions. The result factorizes into two elementary blocks, and solves the classical Yang-Baxter equation. We also determine the corresponding exact factorized S matrix, and show that its perturbative expansion matches our tree-level results, once we correctly identify the deformed light-cone symmetry algebra of the string. Finally, we briefly revisit the computation of the corresponding S matrix for the η deformation based on the distinguished Dynkin diagram, finding a tree-level S matrix that factorizes and solves the classical Yang-Baxter equation, in contrast to previous results.