Near-infrared persistent luminescent particles are appealing
materials
for a diverse range of optoelectronic and biomedical applications.
Thermal treatment at high temperature (e.g., solid-state annealing
process) has been shown to enhance the luminescence intensity of these
particles, while it remains a challenge to manipulate the morphology
and solution dispersibility. Herein, molten salt in situ synthesis of Cr3+-doped zinc gallogermanate (ZGGO) with
well-defined morphology and solution dispersibility is developed in
combination with citric acid. In the absence of the physical grinding
treatment (e.g., mechanically milling), the resulting ZGGO particles
are not only readily dispersible in the aqueous solution but also
exhibit enhanced persistent luminescence. The synergetic effects of
salt and citric acid on the particle formation process as well as
the optical properties are elucidated. Interestingly, these particles
also exhibit enhanced ferromagnetism properties, showing promise for
multiple optical/magnetic applications. The molten salt synthesis
approach demonstrated in this work offers an alternative pathway for
producing persistent luminescent particles, and the method may help
to improve the synthesis of other complex metal oxide particles.