Correlating the structural and magnetic properties of the non-cubic double perovskites with Ir5+ ions

Mohanty, Sipun; Mandal, Sibasish; Sharma, Rishi; Mukherjee, Samrat

doi:10.1016/j.solidstatesciences.2024.107480

Solid State Sciences

2024

DOI: 10.1016/j.solidstatesciences.2024.107480

|View full text |Cite

Correlating the structural and magnetic properties of the non-cubic double perovskites with Ir5+ ions

Sipun Mohanty,

Sibasish Mandal,

Rishi Sharma

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 44 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

A complex magnetic study: evidence of spin-glass transition below long-range magnetic ordering and its correlation with renormalization of phonon modes

Mohanty,

Mukherjee

2024

J. Phys.: Condens. Matter

View full text Add to dashboard Cite

In this paper, we report a complex magnetic behavior arising due to the interplay of three active magnetic cations (Nd/Sm, Co and Ir), forming 3d-5d-4f magnetic sublattices. The B-site ordered double perovskites Nd2CoIrO6 and Sm2CoIrO6 were successfully prepared by conventional solid-state method. Detailed structural analysis revealed that both samples crystallized in monoclinic structure with P21/n (No.-14) space group. XPS analysis confirms the presence of multiple oxidation states of Ir (i.e., Ir4+ and Ir5+). Both samples show a paramagnetic-ferrimagnetic (TFiM) transition around 100 K, additionally, a low temperature transition is observed at around 10 K in the SCIO sample. This FM-like behaviour of the samples is attributed to the antiparallel alignment of the Co2+ and Ir4+ spins, resulting in FIM ordering. The ac susceptibility analysis confirms a spin glass type transition just below the long-range ordering temperature in NCIO sample, The obtained characteristic flipping time of a single spin from both the law (Power law and Vogel-Fulcher law) and nonzero Vogel-Fulcher temperature (T0≃ 89.1 K) further verified the existence of cluster spin-glass behavior below the ordering temperature. The temperature evolution of phonon modes (up to 4 K) suggests that the phonon mode above the magnetic ordering temperature is mainly governed by the lattice degrees of freedom, notable renormalization of the mode frequency below the ordering temperature is due to the coupling of lattice with the underlying magnetic degrees of freedom.

show abstract

A complex magnetic study: evidence of spin-glass transition below long-range magnetic ordering and its correlation with renormalization of phonon modes

Mohanty,

Mukherjee

2024

J. Phys.: Condens. Matter

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Correlating the structural and magnetic properties of the non-cubic double perovskites with Ir5+ ions

Cited by 1 publication

References 44 publications

A complex magnetic study: evidence of spin-glass transition below long-range magnetic ordering and its correlation with renormalization of phonon modes

A complex magnetic study: evidence of spin-glass transition below long-range magnetic ordering and its correlation with renormalization of phonon modes

Contact Info

Product

Resources

About