2021
DOI: 10.48550/arxiv.2111.04948
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Correlating thermodynamics, morphology, mechanics and thermal transport in PMMA-PLA blends

Debashish Mukherji,
Tiago Espinosa de Oliveira,
Celine Ruscher
et al.

Abstract: Thermodynamics controls structure, function, stability and morphology of polymer blends. However, obtaining the precise information about their mixing thermodynamics is a challenging task, especially when dealing with complex macromolecules. This is partially because of a delicate balance between the local concentration/composition fluctuations and the monomer level (multi-body) interactions. In this context, the Kirkwood-Buff (KB) theory serves as a useful tool that connects the local pairwise fluid structure… Show more

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