2020
DOI: 10.1016/j.chemphys.2020.110911
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Correlation between the photocatalytic activity of CdSe nanostructured thin films with optical band gap and Urbach energy

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Cited by 30 publications
(5 citation statements)
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“…The exponential increase of the absorption coefficient near the absorption edge is described by transitions among the band tails, depending on the type of disordering [50] . Higher values of E U tend to lower the transition gap between valance and conduction band which proves quite beneficial for improved electron mobility within the nanomaterials to be used in optoelectronic and catalytic applicabilities [51] .…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The exponential increase of the absorption coefficient near the absorption edge is described by transitions among the band tails, depending on the type of disordering [50] . Higher values of E U tend to lower the transition gap between valance and conduction band which proves quite beneficial for improved electron mobility within the nanomaterials to be used in optoelectronic and catalytic applicabilities [51] .…”
Section: Resultsmentioning
confidence: 99%
“…This was further confirmed by plotting the graph between Eg and E U as depicted in the Figure 8 The exponential increase of the absorption coefficient near the absorption edge is described by transitions among the band tails, depending on the type of disordering. [50] Higher values of E U tend to lower the transition gap between valance and conduction band which proves quite beneficial for improved electron mobility within the nanomaterials to be used in optoelectronic and catalytic applicabilities. [51] Hence, doping of metal atom can alter the E U values and in turn can influence modification of energy band gaps which definitely affects the materials efficiency to be employed in different applications.…”
Section: Urbach Energy (E U )mentioning
confidence: 99%
“… Sr. No. Material E g (eV) Dye Degradation time %age Efficiency References 1 PbSe nanomaterial 2.15 MO 0.5 h 83.13 % [ 48 ] 2 CdSe nanostructured 3.88–1.83 CR 2.5 h 50% [ 49 ] MB 4.5 h 88% 3 Ba 2 AsGaSe 5 1.39 RhB 2.5 h 23% [ 50 ] 4 bismuth selenide 1.2 RB 2 h 90% [ 51 ] CR 35% 5 Bismuth-cobalt selenide 2.35 CR 1.6 h 85% [ 52 ] 6 CdSe/CeO 2 2.61 CR 2.5 h 97.3% [ 53 ] 7 FeSe 2.0 CR 3 h 85.1% [ 54 ] 8 SrBiSbSe 3 2.01 CR 1 h 86.9% [ 55 ] 9 AgInSbSe 3 1.97 CR 1.25 h 77.8% Present study …”
Section: Resultsmentioning
confidence: 99%
“…The scope of this study is constrained by its exclusive reliance on experimental results. Future endeavors could expand the research framework to encompass theoretical analyses, akin to the investigations conducted by Sai in the context of ruthenium alloyed iron pyrite [ [32] , [33] , [34] , [35] , [36] , [37] , [38] , [39] , [40] , [41] , [42] , [43] , [44] , [45] , [46] , [47] , [48] , [49] , [50] , [51] , [52] ]. Additionally, there is potential for investigating the influence of zinc alloying on the properties of .…”
Section: Discussionmentioning
confidence: 99%
“…The pyrite crystal structure, particularly due to its isotropic nature in all three dimensions, presents intriguing applications spanning geochemistry, catalysis, and photovoltaic energy conversion [ [23] , [24] , [25] , [26] , [27] , [28] , [29] ]. Various preparation techniques, including physical vapor deposition (PVD), thermal vapor oxidation/sulfurization [ [30] , [31] , [32] , [33] ], electrochemical deposition [ 25 ], solvothermal reactions [ 34 ], vapor-liquid-solid mechanisms [ 35 ], and spray pyrolysis [ [36] , [37] , [38] ], have been employed to synthesize (X = Se, S) samples.…”
Section: Introductionmentioning
confidence: 99%