Correlation in the statistical analysis of a reverse fourier neutron time-of-flight experiment

Tilli, K. J.

doi:10.1016/0029-554x(82)90851-5

Cited by 6 publications

(1 citation statement)

References 11 publications

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“…with m. as the mean neutron flight time for the nth peak and with D as a constant which (although originally also included among the parameters to be refined) can be derived by using the statistical theory developed for the analysis of reverse-Fourier time-offlight measurements by Tilli (1982).…”

Section: Practical Error Assessment With Some Illustrative Resultsmentioning

confidence: 99%

Assessment of parameter accuracies in profile analysis of white-beam neutron powder diffraction experiments

Pöyry¹,

Tilli²

1983

J Appl Cryst

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One of the problems arising in profile analyses of white-beam powder diffraction experiments is that in order to assess the reliability of the refined structure parameters allowance must be made not only for errors in the actual powder data but also for uncertainties in the various wavelength-dependent corrections involved. As a means for such assessments the present work provides a general method in which the incident white neutron flux spectrum is assumed to be measured and combined with the other wavelength-dependent factors to form a set of effective incident intensities with known statistical properties for the diffraction peaks. Given that appropriate models are used for both the powder spectrum and the effective fluxes, the unknown model parameters and their accuracies can be estimated optimally through a single least-squares fit of the available experimental data. By applying the formalism to a real nickel powder measurement, it was shown that the precision of the parameter estimates may depend considerably on the errors of the wavelength-dependent corrections, unless these are known with much higher accuracies than the diffraction pattern. In the example this proved true especially for the scale factor and the temperature factor.

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