Correlation of Interfacial Tension of Two-Phase Three-Component Systems

Murphy, Nelson F.; Lastovica, John E.; Fallis, J.

doi:10.1021/ie50570a039

Cited by 41 publications

(13 citation statements)

References 9 publications

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“…For the surface tension of n -C 6 H 14 shown in Figure a, agreement between our data and the reference correlation from Mulero et al within relative absolute deviations of 2% is found over the entire temperature range between 283.15 and 473.15 K. The same statement holds also for most of the totally different 41 experimental data sets, including the measurements of Grigoryev et al, which follow our data and the reference correlation up to 473.15 K. At temperatures below 340 K, larger positive and negative deviations from eq , which are up to 7.5% and outside combined uncertainties, are observed for the data measured by Dutoit and Friedrich, Harkins et al, Murphy et al., and Ridgway and Butler . At temperatures above 400 K, the three additional data sets from Skripov and Sinitsyn, Skripov and Firsov, and Bagdasaryan show increasing negative relative deviations from the present work with values up to −9%.…”

Section: Results and Discussionsupporting

confidence: 90%

Liquid Viscosity and Surface Tension ofn-Hexane,n-Octane,n-Decane, andn-Hexadecane up to 573 K by Surface Light Scattering

et al. 2019

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In the present study, the simultaneous and accurate determination of liquid viscosity and surface tension of the n-alkanes n-hexane (n-C6H14), n-octane (n-C8H18), n-decane (n-C10H22), and n-hexadecane (n-C16H34) by surface light scattering (SLS) in thermodynamic equilibrium is demonstrated. Measurements have been performed over a wide temperature range from 283.15 K up to 473.15 K for n-C6H14, 523.15 K for n-C8H18, and 573.15 K for n-C10H22 and n-C16H34. The liquid dynamic viscosity and surface tension data with average total measurement uncertainties (k = 2) of 2.0 and 1.7% agree with the available literature and contribute to a new database at high temperatures. Over the entire temperature range, a Vogel-type equation for the dynamic viscosity and a modified van der Waals equation for the surface tension represent the measured data for the four n-alkanes within experimental uncertainties. By also considering our former SLS data for n-dodecane (n-C12H26) and n-octacosane (n-C28H58), empirical models for the liquid viscosity and surface tension of n-alkanes were developed as a function of temperature and carbon number covering values between 6 and 28. Agreement between these models and reference correlations for additional selected n-alkanes, which were not included in the development procedure, was found.

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Section: Results and Discussionsupporting

confidence: 90%

Liquid Viscosity and Surface Tension ofn-Hexane,n-Octane,n-Decane, andn-Hexadecane up to 573 K by Surface Light Scattering

et al. 2019

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“…On the other hand, it has been reported in the literature that introduction of a surface active solvent such as acetone and acetic acid into a water-oil system can greatly decrease the interfacial tension. 26 THF, a polar molecule composed of a hydrophilic ether group and a hydrocarbon part, is expected to decrease the interfacial tension between water and oil. As measured by the pendant drop method, the interfacial tension between chloroform and water was 33 mN m À1 , whereas addition of 20% THF (volume fraction) into the water phase reduced this value to $9 mN m À1 (ESI †).…”

Section: Resultsmentioning

confidence: 99%

Effects of interfacial tension on formation of poly(ethylene oxide)-block-polystyrene micelles from emulsions

Wang

Zhang

et al. 2015

RSC Adv.

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“…8 is rather poor. The values by Murphy et al 9 are not included in Fig. 4 because the composition of the conjugate phases is not given in the original paper.…”

Section: Resultsmentioning

confidence: 99%

Interfacial Tension Along the Binodal Curve in the Benzene-Ethanol-Water and n-Hexane-Acetone-Water Ternary Systems at 25 °C

Čechová

Bartovská

1996

Collect. Czech. Chem. Commun.

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The surface tensions, interfacial tensions and densities of conjugate solutions of compositions lying in the miscibility gap were measured for two ternary systems, viz. benzene-ethanol-water and n-hexaneacetone-water, at 25 °C.Interfacial and surface phenomena are of considerable importance in situations involving the transfer of matter across liquid-liquid and liquid-vapour interfaces -in adsorption, diffusion, extraction, catalysis, etc. The effect of surface and interfacial tension on such processes was often neglected, not because it was considered unimportant but because tension data were unavailable. Although interfacial and surface tension data exist in the literature for many two-component liquid-liquid systems, information on three-component systems is scarce and only few papers give interfacial and surface tension data for conjugate phases simultaneously.In the present paper, interfacial and surface tension values as well as density values are reported for two three-component two-phase systems, viz. benzene-ethanol-water (BEW) and n-hexane-acetone-water (HAW) at 25 °C, with a view to enriching the volume of experimental data in this field of interest. EXPERIMENTAL ChemicalsAll the chemicals, i.e. benzene and acetone of analytical grade, and n-hexane, n-heptane, and ethanol for UV spectroscopy, were supplied by Lachema Brno, Czech Republic. Prior to measurement, the Ternary Systems

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Correlation of Interfacial Tension of Two-Phase Three-Component Systems

Cited by 41 publications

References 9 publications

Liquid Viscosity and Surface Tension ofn-Hexane,n-Octane,n-Decane, andn-Hexadecane up to 573 K by Surface Light Scattering

Liquid Viscosity and Surface Tension ofn-Hexane,n-Octane,n-Decane, andn-Hexadecane up to 573 K by Surface Light Scattering

Effects of interfacial tension on formation of poly(ethylene oxide)-block-polystyrene micelles from emulsions

Interfacial Tension Along the Binodal Curve in the Benzene-Ethanol-Water and n-Hexane-Acetone-Water Ternary Systems at 25 °C

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