Correlations of Vapour-Liquid Critical Point Parameters of Alkali Metals

Ramasamy, Balasubramanian

doi:10.1252/jcej.37.1415

J. Chem. Eng. Japan

2004

DOI: 10.1252/jcej.37.1415

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Correlations of Vapour-Liquid Critical Point Parameters of Alkali Metals

Balasubramanian Ramasamy

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Cited by 5 publications

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Correlations of supercritical temperature of fluid alkali metals

Balasubramanian¹

2008

Asia-Pacific J Chem Eng

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The supercritical temperature, the maximum attainable temperature of superheating and the critical compressibility factor of caesium, rubidium and potassium are correlated through the generalised van der Waals equation of state. This three-parameter equation differs from the known van der Waals equation of state by the modified expression for molecular pressure. For caesium, rubidium and potassium, the ratios of the supercritical temperature to the maximum attainable temperature of superheating are estimated. Our estimation results are in agreement with experimental data. It has been established that caesium, rubidium and potassium obey the single-parameter law of corresponding states with the ratio of the supercritical temperature to the maximum attainable temperature of superheating as the thermodynamic similarity parameter. 

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Correlations of supercritical temperature of fluid alkali metals

Balasubramanian¹

2008

Asia-Pacific J Chem Eng

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Correlations of attainable superheat of fluid alkali metals

Balasubramanian¹

2007

Journal of Nuclear Materials

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A study on the correlations of supercritical temperature of fluid alkali metals based on the generalised van der Waals equation of state

Balasubramanian¹

2010

Journal of Molecular Liquids

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Correlations of Vapour-Liquid Critical Point Parameters of Alkali Metals

Cited by 5 publications

References 8 publications

Correlations of supercritical temperature of fluid alkali metals

Correlations of supercritical temperature of fluid alkali metals

Correlations of attainable superheat of fluid alkali metals

A study on the correlations of supercritical temperature of fluid alkali metals based on the generalised van der Waals equation of state

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