Corrigendum to “Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts” [Coord. Chem. Rev. 374 (2018) 173–217]

Solar-driven CO2 to CO reduction utilizing H2O as an electron donor by earth-abundant Mn–bipyridine complex and Ni-modified Fe-oxyhydroxide catalysts activated in a single-compartment reactor

“…Many Mn-complexes have been reported for electrochemical or photocatalytic CO 2 reduction. [9][10][11][12] We have reported that a Mn-complex polymer (hereinafter referred to as [Mn-MeCN]) on multi-walled carbon nanotubes (MWCNTs) facilitated electrocatalytic CO 2 reduction in a mixed aqueous solution of potassium borate and sulfate (hereinafter referred to as KBB) with near neutral pH, while the bare Mn-complex did not function as a catalyst in the same solution. 11 The overpotential of electrocatalytic CO 2 reduction over [Mn-MeCN] was significantly reduced to 100 mV by the synergetic effect of the MWCNT support and K + cations.…”

Nature-inspired electrocatalysts and devices for energy conversion

“…Thorough reviews about molecular catalysts for reduction of CO 2 are available elsewhere. [343][344][345]…”

Selective synthesis and crystal structures of manganese(I) complexes with a bi- or tridentate terpyridine ligand

“…Carbonylmanganese(I) complexes with polypyridyl ligands are of particular interest as novel active molecules that are able to release CO in response to photoirradiation (Carrington et al, 2013;Chakraborty et al, 2014;Jimenez et al, 2015) or as electrocatalysts of CO 2 reduction (Grills et al, 2018;Stanbury et al, 2017). Among these compounds, studies have concentrated mainly on tricarbonyl complexes comprising bidentate polypyridyl supporting ligands; by contrast, only few reports exist on dicarbonyl complexes bearing tridentate ligands (Compain et al, 2015;Machan & Kubiak, 2016).…”