1995
DOI: 10.1016/0022-328x(95)05682-f
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Corrigendum to the paper “Bis(di-t-butylphosphino) methane complexes of rhodium: homogeneous alkyne hydrosilylation by catalyst-dependent alkyne insertion into RhSi or RhH bonds. Molecular structures of the dimer [(dtbpm)RhCl]2 and of the silyl complex (dtbpm) Rh[Si(OEt)3](PMe3)” [J. Organomet. Chem., 490 (1995) 51–70]

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Cited by 26 publications
(38 citation statements)
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“…The crystal structures of all three new molybdenum complexes were carried out ( (2) 150 (2) 150 (2) 150 (2) 150 (2) 150 (2) 150 (2) 150 (2) 150(2) a (Å ) 9.4418 (6) 12.1290 (6) 17.8552 (12) 11.8877 (11) 18.3477 (13) 18.3539 (11) 18.7960 (13) 8.7614 (7) 11.3002(9) b (Å ) 17.3456 (11) 13.7921 (7) 9.6650 (6) 13.9578 (13) 15.5405 (11) 15.4842 (9) 15.8810 (11) 20.7393 (15) 16.5626(13) c (Å ) 18.3159 (11) 18.0899 (10) 19.4329 (13) 18.6855 (18) representative example is shown in Fig. 4.…”
Section: Resultsmentioning
confidence: 97%
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“…The crystal structures of all three new molybdenum complexes were carried out ( (2) 150 (2) 150 (2) 150 (2) 150 (2) 150 (2) 150 (2) 150 (2) 150(2) a (Å ) 9.4418 (6) 12.1290 (6) 17.8552 (12) 11.8877 (11) 18.3477 (13) 18.3539 (11) 18.7960 (13) 8.7614 (7) 11.3002(9) b (Å ) 17.3456 (11) 13.7921 (7) 9.6650 (6) 13.9578 (13) 15.5405 (11) 15.4842 (9) 15.8810 (11) 20.7393 (15) 16.5626(13) c (Å ) 18.3159 (11) 18.0899 (10) 19.4329 (13) 18.6855 (18) representative example is shown in Fig. 4.…”
Section: Resultsmentioning
confidence: 97%
“…CO)4 (dcpm)](17) and [W(CO) 4 (dcpm)](18) in moderate isolated yields upon thermolysis of the free ligand and cis-[M(CO) 4 (NHC 5 H 10 ) 2 ] in dichloromethane. Both are easily characterised, IR spectra showing the characteristic tetracarbonyl pattern being shifted by around 12-15 cm À1…”
mentioning
confidence: 99%
“…While a genuine trans-chelator like TRANSDIP only binds one metal centre at a time, WIDEPHOS is capable of accommodating up to two metal centres. 89 Bimetallic complexes are ubiquitous in catalysis and molecular recognition, [134][135][136][137][138][139] but the confinement of two metal centres within a molecular cavity, [140][141][142][143] as much as diphosphines designed to bring two metal centres close together are a rare occurrence. 111,[144][145][146] Because of the unique location of the two P(III) donor atoms within the rigid macrocyclic framework, the binding of one metal centre strongly influences the coordination behaviour of the second donor atom in dinuclear complexes of WIDEPHOS.…”
Section: Dalton Transactions Perspectivementioning
confidence: 99%
“…His research interests combined all three fields, with a focus on homogeneous catalysis with transition metal complexes. Bidentate donor ligands with a small bite angle such as bis(di- tert -butylphosphino)methane (dtbpm) were a unique feature of his work [61,67,7072 8081 84,86,9394 97,100101 103,107,124,128,148149] that ultimately enabled C–Si activation of organosilanes and the C–C activation of oxiranes by coordinatively unsaturated platinum species [66,149]. In the mechanism of the Dötz reaction, he found that chromacyclobutene structures were unrealistic intermediates and instead proposed vinylcarbene complexes as much more stable isomers [64,68,88].…”
Section: Peter Hofmann a Multifaceted Organometallic Chemistmentioning
confidence: 99%