Six safety initiatives have been identified for accelerating the resolution of waste tank safety issues and closure of unreviewed safety questions. These initiatives are key drivers for building and maintaining the momentum to correct tank farm problems. Safety Initiative 5 is to reduce safety and environmental risk from tank leaks. Item d of Safety Initiative 5 is to complete corrosion studies of single-shell tanks to determine failure mechanisms and corrosion control options to minimize further degradation by June 1994. This report has been prepared to fulfill Safety Initiative 5, Item d. The corrosion mechanisms that apply to Hanford Site single-shell tanks are stress corrosion cracking, pitting/crevice corrosion, uniform corrosion, hydrogen embrittlement, and microbiologically influenced corrosion. Accurate determination of single-shell tank failure mechanisms involves laboratory experiments using synthetic wastes to simulate the wastes in the singleshell tanks coupled with the destructive and non-destructive examination of single-shell tanks to compare the laboratory data with the actual corrosion of the tanks. The corrosion data relevant to the single-shell tanks dates back three decades, when results were obtained from in-situ corrosion coupons in a few single-shell tanks. Since that time there have been intertank transfers, evaporation, and chemical alterations of the waste. These activities have changed the character and the present composition of the waste is not well characterized.