Corrosion Behavior of Alkyd-Resin-Coated Carbon Steel under Cathodic Polarization in Both Static and Flowing Seawater

Abstract

The effect of cathodic polarization on the corrosion behavior of alkyd-resin-coated carbon steel with an artificial coating defect was researched using a wire beam electrode (WBE) and electrochemical impedance spectroscopy (EIS) in both static and flowing simulated solutions. The microscopic morphology and chemical structure of the organic coating were characterized by scanning electron microscopy (SEM) and infrared spectroscopy (FT-IR) to reveal the degradation mechanisms of organic coatings under different polarization potentials. The study found that the failure process of the alkyd coating could be accelerated by cathodic polarization. After 312 h of immersion, the impedance under −1100 mV was one order of magnitude lower than that under the open-circuit potential (OCP). The coating delamination became serious with the negative shifting of polarization potential, and the delamination area ratio under −1100 mV in both static and flowing seawater rose to 23% and 14%, respectively. Interestingly, the flowing condition of the immersion solution that combined with cathodic polarization exhibited a synergistic effect, which could accelerate (in the earlier stage) and then alleviate the delamination of the coating. Furthermore, the results showed that both the diffusion of the corrosion particles and the anodic dissolution reaction of the metal could be significantly affected by cathodic polarization and the flowing condition of the solution, which provides a possible approach to gain insight into the delamination of organic coating.

Electrochemical Behavior of Carbon Steel ASTM A36 in Diluted Pregnant Leach Solutions from Electrowinning of Copper

“…The EIS measurement at initial time is subjected to the most unstable condition since a rapid oxide layer forms over the bare metal surface. In contrast, 𝑅 values for rotation presents almost null values, which indicates that ohmic resistance decreases with rotation [29].…”