The effect of temperature on the galvanic corrosion behavior of SA106 Gr.B carbon-manganese steel was studied in an alkaline aqueous solution at various temperatures (30, 60, and 90 °C) via electrochemical corrosion tests. At all temperatures studied, carbon-manganese steel acted as the anode of the galvanic cell composed of carbon-manganese steel and magnetite because the corrosion potential of carbon-manganese steel was significantly lower than that of magnetite. The corrosion current density of carbon-manganese steel significantly increased due to the galvanic effect irrespective of temperature used in this study. With the increase in temperature, the extent of the galvanic effect on the corrosion current density of carbon-manganese steel and reductive dissolution of magnetite gradually increased. When the area ratio of magnetite to carbon-manganese steel increased, the corrosion rate of the carbon-manganese steel in contact with magnetite further increased.