Stainless steels and alloys are characterized primarily by their corrosion resistance, high strength, ductility, etc. used for various advanced applications like automotive and aerospace, sugar refineries, construction materials, etc. Many advanced high-speed machineries /systems need fine quality of parts to provide good performance in its working conditions. The machining of stainless steel and its alloys is of interest, because, of its excellent mechanical properties. Stainless steels and alloys are machined generally by traditional machining processes. But complex shapes and features on products are difficult task with the use of traditional metal cutting techniques. To machine the advanced materials to produce high dimensional accuracy and generation of intricate shapes in difficult-to-machine materials like stainless steels and alloys, nontraditional machining (NTM) techniques are now attractive the viable choices. To attain improved machining performance of the NTM processes, it is always necessary to find the optimal combinations of various process input parameters of those processes. In the present chapter, some aspects of machining of stainless steel and alloys using NTM processes such as electric discharge machining (EDM) and wire EDM, are discussed and some concluding remarks have been drawn from the study.