Corrosion inhibition efficiency of Gemini surfactant 1,4-butan-bis-dimethyl dodecyl ammonium bromide (designed as 12-4-12), 1,4-butan-bis-dimethyl tetradecyl ammonium bromide (designed as 14-4-14), conventional surfactants dodecyl thrimethyl ammonium bromide (DTAB) and tetradecyl thrimethyl ammonium bromide (TTAB) on low carbon steel is investigated using three common methods namely, weight loss, open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS). The influence of chain length and temperature of the media is verified. Data indicate that, the corrosion inhibition efficiency is improved by increasing the concentration and chain length of the surfactants. Corrosion rate of steel increases by increasing the temperature of the medium containing surfactant. Adsorption isotherm of used surfactants and kinetic parameters are studied.