Rain is one of the main importance issues for atmospheric corrosion problem. Effects of rainfall on corrosion behaviors of carbon steels were investigated using artificial rainfall equipment. Three types of Atmospheric Corrosion Monitoring (ACM) sensors, which consist of Fe-Ag, Zn-Ag, and Al-Ag galvanic couples, were used to illustrate the correlation between the sensors output, Corrosion Rate (CR), and chemical concentration in the rain. The effects of ionic species on the corrosion behaviors were observed by using NaCl, KCl, Na 2 SO 4 , NaNO 3 , and KNO 3 as rainfall solutions. The result revealed that the rainfall rate was insensitive to ACM sensors outputs and CRs. In contrast, the chemical species and their concentrations in the rainfall solution significantly affected the ACM outputs and CRs. The corrosivity of the cations (Na + and K + ) is negligible compared to the anions (Cl -, SO 4 2-, NO 3 -).For a given number of molar concentration, the CRs resulted from the corrosivity of SO 4 -2 anions were higher than that of Cland NO 3 -anions, respectively. According to the empirical data, the CRs is increased and then reach a steady state as the molar concentration is continuously increased. This research also indicates that the ACM sensors outputs of Fe-Ag and Zn-Ag couples are capable of estimating corrosivity of the atmosphere, while the ACM sensor of Al-Agcouple can be used to determine not only the time of wetness but also the typeofchemical species in the environment. The research methods discussed in this paper proves that the CRs are dependent on the atmospheric composition and can be forecasted through ACM sensors.