2014
DOI: 10.1149/2.019408jes
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Corrosion of Steel Embedded in Fly Ash Mortar Using a Transmission Line Model

Abstract: Electrochemical impedance spectroscopy was used to study the corrosion behavior of reinforcing steel embedded in alkaline activated fly ash mortar with chloride pollution. The porous nature of the rust layer was studied using a transmission line model and the parameters of the interfacial oxide/hydroxide film were determined by interpretation of the impedance data using a cylindrical pore. The rust layer generated on the steel surface was studied at the end of the experiment (two years) using scanning electron… Show more

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Cited by 9 publications
(6 citation statements)
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“…Table 3 includes EIS data fitting results with an average relative error <10% for each EEC used and a χ 2 ranging from 2 × 10 −3 to 7 × 10 −4 . A CPE unit is used in place of a C dl due to the non-ideal capacitance behaviour, and its impedance is given by: Z CPE = ( Y ) −1 ( jω ) − n , where Y is the admittance (S cm –2 s 1−n ); ω is the angular frequency (rad s –1 ), j 2 = (−1); and n (−1 < n < +1) is a dimensionless exponent related with surface irregularity and electric field distribution [37,38]. The R s parameter presents a low and constant value (∼65 Ω cm 2 ) see Table 3, indicating a low ohmic drop between the working electrode and the reference electrode in the 3.5 wt.% NaCl supporting electrolyte.…”
Section: Discussionmentioning
confidence: 99%
“…Table 3 includes EIS data fitting results with an average relative error <10% for each EEC used and a χ 2 ranging from 2 × 10 −3 to 7 × 10 −4 . A CPE unit is used in place of a C dl due to the non-ideal capacitance behaviour, and its impedance is given by: Z CPE = ( Y ) −1 ( jω ) − n , where Y is the admittance (S cm –2 s 1−n ); ω is the angular frequency (rad s –1 ), j 2 = (−1); and n (−1 < n < +1) is a dimensionless exponent related with surface irregularity and electric field distribution [37,38]. The R s parameter presents a low and constant value (∼65 Ω cm 2 ) see Table 3, indicating a low ohmic drop between the working electrode and the reference electrode in the 3.5 wt.% NaCl supporting electrolyte.…”
Section: Discussionmentioning
confidence: 99%
“…Besides, propagation stage is favor by relative humidity, oxygen and temperature, and is defined by the appearance of the first visible crack on the concrete cover surface, then multiple cracks develop until delamination is found. To quantify the corrosion damage nondestructive electrochemical techniques have been used (Song, 2000;González, 2007;Fajardo et al, 2014).…”
Section: Introductionmentioning
confidence: 99%
“…Reinforced concrete (RC) is one of the most widely used materials in the construction sector because of its versatility, cost and durability. The highly alkaline environment (pH above 12.5) of a good quality concrete leads to the formation of a passive layer on the embedded steel rebar, protecting it from corrosion and assuring a low steel corrosion rate of less than 1.16 μm/year (González et al, 1996;García et al, 2012;Fajardo et al, 2014). However, this protective passive layer can be disrupted when the pH of the concrete pore solution is lowered, e.g.…”
Section: Introductionmentioning
confidence: 99%