The diffusion processes during the contact melting at the boundary of explosively welded VT1-0 titanium with CuNi19 (melchior) and CuNi45 (constantan) alloy composites were studied. Heat treatment of composites led to the formation of the interaction zone at the joint boundary. The interaction zone in VT1-0 + CuNi19 consists of TiCuNi and αTi + Ti2Cu(Ni) continuous layers as well as a mixture of TiNi(Cu) + TiCu(Ni) + Ti2Cu(Ni) intermetallics. It has been shown that an increase in the nickel content in the case of VT1-0 + CuNi45 composite leads to a decrease in the temperature of contact melting, a change in its mechanism, an increase in the titanium content in the interaction zone, and the appearance of additional Ti2Ni(Cu) intermetallic in its composition.