“…On the other hand, the image by 200 ppm inhibitor showed smoother and less dissolution highlighting the passive film formation and the active sites obstruction. As confirmed by the surface specifications, the protective layer on the metal led to a significant reduction in the corrosion rate 62 . Figure 13 Optical microscopy images of Al alloy surface after 24 h immersion in 3.5% NaCl solution in the ( a ) absence, ( b ) presence of RA/AgNPs, respectively.…”
Section: Resultsmentioning
confidence: 65%
“…On the other hand, the image by 200 ppm inhibitor showed smoother and less dissolution highlighting the passive film formation and the active sites obstruction. As confirmed by the surface specifications, the protective layer on the metal led to a significant reduction in the corrosion rate 62 .…”
Asymmetric Configuration (As-Co) in the electrochemical noise (EN) was used to evaluate Ranunculus Arvensis / silver nanoparticles (RA/Ag NPs) as corrosion inhibitor for aluminum alloy (AA 2030) when gets exposed to 3.5% NaCl media. The ECN results of Asymmetric Configuration (As-Co) and Symmetric Configuration (Sy-Co) were interpreted using wavelet and statistical methods. The standard deviation of partial signal (SDPS) plots derived using of wavelet. The SDPS plot of As-Co demonstrated that the quantity of electric charge (Q) decreased with the addition of the inhibitor up to the optimum amount (200 ppm) due to the decreased corrosion rate. Moreover, the use of As- Co leads to record signal of one electrode and prevent recording extra signals arising from two identical electrodes which confirmed by the statistical parameters. The As-Co made of Al alloys were more satisfactory for estimating inhibiting effect of RA/Ag NPs compared to Sy-Co. Besides, aqueous extract of Ranunculus Arvensis (RA) plant as reducing agent mediates the synthesis of silver nanoparticles (RA/Ag NPs). The prepared NPs have been elaborately characterized using Field-Emission Scanning Electron Microscopy (FESEM), X-Ray Diffraction (XRD) analysis, and Fourier-Transform Infrared Spectroscopy (FT-IR) that revealed suitable synthesize of the RA/Ag NPs.
“…On the other hand, the image by 200 ppm inhibitor showed smoother and less dissolution highlighting the passive film formation and the active sites obstruction. As confirmed by the surface specifications, the protective layer on the metal led to a significant reduction in the corrosion rate 62 . Figure 13 Optical microscopy images of Al alloy surface after 24 h immersion in 3.5% NaCl solution in the ( a ) absence, ( b ) presence of RA/AgNPs, respectively.…”
Section: Resultsmentioning
confidence: 65%
“…On the other hand, the image by 200 ppm inhibitor showed smoother and less dissolution highlighting the passive film formation and the active sites obstruction. As confirmed by the surface specifications, the protective layer on the metal led to a significant reduction in the corrosion rate 62 .…”
Asymmetric Configuration (As-Co) in the electrochemical noise (EN) was used to evaluate Ranunculus Arvensis / silver nanoparticles (RA/Ag NPs) as corrosion inhibitor for aluminum alloy (AA 2030) when gets exposed to 3.5% NaCl media. The ECN results of Asymmetric Configuration (As-Co) and Symmetric Configuration (Sy-Co) were interpreted using wavelet and statistical methods. The standard deviation of partial signal (SDPS) plots derived using of wavelet. The SDPS plot of As-Co demonstrated that the quantity of electric charge (Q) decreased with the addition of the inhibitor up to the optimum amount (200 ppm) due to the decreased corrosion rate. Moreover, the use of As- Co leads to record signal of one electrode and prevent recording extra signals arising from two identical electrodes which confirmed by the statistical parameters. The As-Co made of Al alloys were more satisfactory for estimating inhibiting effect of RA/Ag NPs compared to Sy-Co. Besides, aqueous extract of Ranunculus Arvensis (RA) plant as reducing agent mediates the synthesis of silver nanoparticles (RA/Ag NPs). The prepared NPs have been elaborately characterized using Field-Emission Scanning Electron Microscopy (FESEM), X-Ray Diffraction (XRD) analysis, and Fourier-Transform Infrared Spectroscopy (FT-IR) that revealed suitable synthesize of the RA/Ag NPs.
“…Both anodic and cathodic curves have a mixed inhibitor character, which is a sign that corrosion current density is moving in the direction of lower value . According to Table , different anodic and cathodic current densities were observed following the addition of a corrosion inhibitor, proving that lupine extract is a mixed-type corrosion inhibitor . Lupine extract adsorption on Cu surfaces is indicated by the fact that i corr values decrease as inhibitor concentrations rise (Table ).…”
Section: Resultsmentioning
confidence: 94%
“… 51 According to Table 2 , different anodic and cathodic current densities were observed following the addition of a corrosion inhibitor, proving that lupine extract is a mixed-type corrosion inhibitor. 52 Lupine extract adsorption on Cu surfaces is indicated by the fact that i corr values decrease as inhibitor concentrations rise ( Table 2 ). The difference between the inhibitor and inhibitor-free settings in terms of corrosion potential ( E corr ) is less than 85 mV, which suggests a combination of inhibitor-free circumstances.…”
Copper corrosion was suppressed when a lupine extract
was immersed
in a 2 M sulfamic acid (H
2
NSO
3
H) solution. Numerous
methods, including mass loss (ML), dynamic potential polarization
(PL), and electrochemical impedance (EIS), were employed in these
experiments, in addition to theoretical computations such as density
functional theory (DFT), Fukui function, and Monte Carlo simulations.
Fourier transform infrared (FT-IR) spectroscopy and scanning electron
microscopy (SEM) were used to analyze the Cu surface’s composition
and determine its form. Mass loss (ML) was used to examine the inhibition
rate of copper corrosion in sulfamic acid at 25 °C in the presence
of lupine extract. After examining how it behaved throughout the adsorption
process on copper, it was discovered that it follows the Langmuir
isotherm and chemical adsorption. An analysis of the PL curves indicates
that the lupine extract is a mixed-type inhibitor. It was shown that
the inhibitory efficiency increased to 84.2% with increasing lupine
concentration. Additionally, as the data show, the efficiency of inhibitors
is diminished by increasing temperatures. Theoretical calculations
and experimental data were compared using Monte Carlo simulation (MC)
and density functional theory (DFT).
“…The Nyquist plot consists of a depressed semicircle in the uninhibited (blank) solution. This indicates that the corrosion process of metal (mild steel) in 1.0 M HCl is generally charge transfer controlled [14,15].…”
Section: Eis Lpr and Potentiodynamic Polarization Experimentsmentioning
The role of Citrus aurantium fruit peel extract solution in the existing research is to investigate the effect as corrosion inhibitor on mild steel in the atmospheric environment with its eco-friendly and green effect. It was studied the inhibitor effect of Citrus aurantium utilizing linear polarization (LPR), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) methods. The working electrodes were immersed in HCl solutions containing various concentrations of Citrus aurantium fruit peels extract in order to equilibrate the metal-solution interface for one hour before each measurement. The bitter orange fruit peels extract indicated a potent inhibitor influence as a consequence of one hour electrochemical tests, and with the raise of extract concentrations of Citrus aurantium fruit peels, the protection influence of mild steel electrodes in HCl solutions also enhanced. Finally, the surface morphologies of the working electrodes in aggressive HCl solutions without and with bitter orange fruit peels extract after one-hour immersion were analysed by an optical microscopy, it was concluded that the mild steel surface in the Citrus aurantium fruit peels extract solution had a flawless surface compared to the blank one. Experimental data and surface morphology results are highly consistent with each other.
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