2013
DOI: 10.1155/2013/142493
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Corrosion Protection of AA7075 Aluminium Alloy by Trimethoxy-Silanes Self-Assembled Monolayers

Abstract: This study presents electrochemical data concerning the aluminium alloy AA7075 surface modified by self-assembled monolayers (SAMs) of octadecyl-trimethoxy-silane and propyl-trimethoxy-silane. Polarisation curves have shown SAMs blocking effect, as they partially block the oxygen reduction reaction and displace the corrosion potential to positive values. Electrochemical impedance spectroscopy experiments have suggested that the protective effect comes from the oxide layer stabilization by the organic monolayer… Show more

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Cited by 11 publications
(8 citation statements)
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“…Landing gear components are typically manufactured with advanced materials using conventional metallic materials such as aluminum alloy 7075 [22][23][24][25][26][27][28][29][30], alloys steel 4340 [31][32][33][34][35][36], titanium 6Al-4V [37][38][39][40][41][42], titanium 6Al-6V-2Sn [43,44], titanium 15Al-3Cr-3Al-3Sn [45][46][47], and titanium 10Al-2Fe-3V [48][49][50][51][52]. The most versatile titanium alloys in the aerospace industry are titanium 6Al-4V, titanium 6Al-6V-2Sn, titanium 15Al-3Cr-3Al-3Sn, and titanium 10Al-2Fe-3V because of their excellent properties.…”
Section: Background/motivationmentioning
confidence: 99%
“…Landing gear components are typically manufactured with advanced materials using conventional metallic materials such as aluminum alloy 7075 [22][23][24][25][26][27][28][29][30], alloys steel 4340 [31][32][33][34][35][36], titanium 6Al-4V [37][38][39][40][41][42], titanium 6Al-6V-2Sn [43,44], titanium 15Al-3Cr-3Al-3Sn [45][46][47], and titanium 10Al-2Fe-3V [48][49][50][51][52]. The most versatile titanium alloys in the aerospace industry are titanium 6Al-4V, titanium 6Al-6V-2Sn, titanium 15Al-3Cr-3Al-3Sn, and titanium 10Al-2Fe-3V because of their excellent properties.…”
Section: Background/motivationmentioning
confidence: 99%
“…The studies present conflicting results for exposure periods exceeding 360 min. The substitution of self-assembled monolayers as an alternate for coatings on aluminum has been investigated in recent years [96,97]. It is to be re-called that the molecules which constitute SAM have three major characteristics: a.…”
Section: Effect Of Hydrophobic Surface On the Corrosion Resistance Ofmentioning
confidence: 99%
“…An example is the use of layers formed via sol‐gel technology . The application of organic silane derivatives in thin film can also prevent the aluminum from corrosion . In other cases, amphiphilic molecules form molecular films on the metal surface, and control the dissolution of aluminum .…”
Section: Introductionmentioning
confidence: 99%
“…Controversially, the carboxylic, phosphonic, and sulfonic acids form SAM layers only on oxide film of metals. Phosphonic acid SAMs are increasingly used for building thin films due to their ability to form well defined and stable layers on oxide surfaces . As a native oxide film covers almost all engineered metals, the application of organic SAM coatings for corrosion protection is of high technological importance .…”
Section: Introductionmentioning
confidence: 99%