We point out that a modified temperature–redshift relation (T-z relation) of the cosmic microwave background (CMB) cannot be deduced by any observational method that appeals to an a priori thermalisation to the CMB temperature T of the excited states in a probe environment of independently determined redshift z. For example, this applies to quasar-light absorption by a damped Lyman-alpha system due to atomic as well as ionic fine-splitting transitions or molecular rotational bands. Similarly, the thermal Sunyaev-Zel’dovich (thSZ) effect cannot be used to extract the CMB’s T-z relation. This is because the relative line strengths between ground and excited states in the former and the CMB spectral distortion in the latter case both depend, apart from environment-specific normalisations, solely on the dimensionless spectral variable x=hνkBT. Since the literature on extractions of the CMB’s T-z relation always assumes (i) ν(z)=(1+z)ν(z=0), where ν(z=0) is the observed frequency in the heliocentric rest frame, the finding (ii) T(z)=(1+z)T(z=0) just confirms the expected blackbody nature of the interacting CMB at z>0. In contrast to the emission of isolated, directed radiation, whose frequency–redshift relation (ν-z relation) is subject to (i), a non-conventional ν-z relation ν(z)=f(z)ν(z=0) of pure, isotropic blackbody radiation, subject to adiabatically slow cosmic expansion, necessarily has to follow that of the T-z relation T(z)=f(z)T(z=0) and vice versa. In general, the function f(z) is determined by the energy conservation of the CMB fluid in a Friedmann–Lemaitre–Robertson–Walker universe. If the pure CMB is subject to an SU(2) rather than a U(1) gauge principle, then f(z)=1/41/3(1+z) for z≫1, and f(z) is non-linear for z∼1.