2014
DOI: 10.1107/s2053229614005725
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Counter-anion role in the formation of two supramolecular complexes: [Ag2(DPP)2](ClO4)2·CH3CN and [Ag2(DPP)2(NO3)2] {DPP isN-[(diphenylphosphanyl)methyl]pyridin-4-amine}

Abstract: The title compounds, bis{μ-N-[(diphenylphosphanyl)methyl]pyridin-4-amine-κ(2)N(1):P}disilver bis(perchlorate) acetonitrile monosolvate, [Ag2(C18H17N2P)2](ClO4)2·CH3CN, (1), and bis{μ-N-[(diphenylphosphanyl)methyl]pyridin-4-amine-κ(2)N(1):P}bis[(nitrato-κ(2)O,O)silver], [Ag2(C18H17N2P)2(NO3)2], (2), each contain disilver macrocyclic [Ag2(C18H17N2P)2](2+) cations lying about inversion centres. The cations are constructed by two N-[(diphenylphosphanyl)methyl]pyridin-4-amine (DPP) ligands linking two Ag(+) cations… Show more

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