The dynamic capture of electrons in a semiconductor quantum dot (QD) by raising a potential barrier is a crucial stage in metrological quantized charge pumping. In this work, we use a quantum point contact (QPC) charge sensor to study errors in the electron capture process of a QD formed in a GaAs heterostructure. Using a two-step measurement protocol to compensate for 1/f noise in the QPC current, and repeating the protocol more than 10 6 times, we are able to resolve errors with probabilities of order 10 −6 . For the studied sample, one-electron capture is affected by errors in ∼ 30 out of every million cycles, while two-electron capture was performed more than 10 6 times with only one error. For errors in one-electron capture, we detect both failure to capture an electron, and capture of two electrons. Electron counting measurements are a valuable tool for investigating non-equilibrium charge capture dynamics, and necessary for validating the metrological accuracy of semiconductor electron pumps.