The fine structure observed in the α decay of deformed platinum isotopes is investigated using the recently developed five-channel formalism, based on the coupled-channel Schrödinger equation with outgoing wave boundary conditions. The internal effect of daughter states is taken into account in dealing with the interaction matrix and the α-cluster formation. The available experimental data concerning α-decay half-lives and fine structures are reproduced. Some predictions are made especially for the α decay of neutron-rich isotopes, which could guide future experiments.Alpha decay is one of the oldest subjects of study in nuclear physics, and continual attention has been paid to its importance from both experimental and theoretical sides. The half-lives of α emitters provide information on the stability of nuclides, especially for superheavy nuclei, while the decay energies pose a tough test for nuclear-mass models and provide direct information on the excitation energy of final daughter states. Theoretically, the main focus of recent investigations has been on the fine structure observed in α decay, where the decay proceeds from the ground states of the parent nucleus to various members of the regular ground-state rotational band in the daughter system. The available theoretical approaches for deformed systems can be divided into two groups, namely, semiclassical and coupledchannels. Some semiclassical methods, based on the onedimensional Wentzel-Kramers-Brillouin (WKB) semiclassical approximation, have been extended from the spherical picture to a deformed case in a phenomenological manner, such as the simple WKB barrier penetration approach [1], the generalized liquid drop model (GLDM) [2], and the unified model for α decay and α capture (UMADAC) [3]. The other group uses the stationary coupled-channels approach [4][5][6][7][8], where the three-dimensional Schrödinger equation is exactly solved with outgoing wave boundary conditions. The second approach is less documented than the semiclassical calculation. Recently, within the coupled-channels framework, we have employed two different techniques to deal with the coupling interaction matrix between channels. We have performed separate four-channel and five-channel calculations for well-deformed rotational α emitters [7,8]. The theoretical results reproduced well the available experimental data concerning α-decay halflives and fine structures. It was also found that semiclassical calculations have a tendency to overrate branching ratios for excited 4 + states by one order of magnitude, while the coupled-channels analysis gives a satisfactory description because of the inclusion of the coupling effect between channels. * From the experimental side, besides considerable progress in the synthesis of new superheavy elements [9,10], improvements have been made for long-living rare α emitters [11][12][13]. Along with the enhancement of experimental sensitivity, some new data have been measured with improved accuracy and some have even been observed for the first time,...