Abstract:We propose a canonical finite strain theory for diffusion-mechanics coupling for the intercalation induced stress generation in Li-ion electrode particles. The intrinsic coupling arises from both mechanical pressure gradient-induced diffusion of Li-ion particles and diffusion induced swelling/shrinkage leading to mechanical stresses. In addition, we extend the finite strain theory for diffusion-mechanics coupling to chemomechanical fracture of electrode particles by introducing a nonlocal crack phase field whi… Show more
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