This study incorporated the index decomposition analysis to drive the GHGs emissions intensity and separate the impact into true efficiency and structural transformation of economic activities on GHGs emissions. The global perspective is investigated in three aspects; (i) global groups of countries regarding income level, (ii) global countries bifurcated into geo-political regions and, (iii) hundred countries are taken to perform individual country level analysis, by taking 20 years (2000–2019) data. The hundred countries are ranked regarding GHGs intensity, efficiency and economic activities with respect to (i) for the latest year performance, (ii) twenty years average performance and, (iii) annual average reduction of GHGs emissions, comparable with base year 2000. Income-based countries groups explicate the improvement of GHGs intensity for HIC only and the economic transformation contributed to it. Efficiency index for all income groups while economic activities of LMIC, MIC and UMIC deteriorated the GHGs emissions. Global geo-political regions explicate the mixed pattern of GHGs intensity. Efficiency index is best for Azerbaijan and least for Uzbekistan. While ranking average GHGs emission reduction countries; Zimbabwe is the best and Qatar is the last country in the intensity list.