Covalent copper-organic frameworks with light-activable catalytic centers as smart artificial enzymes for highly sensitive and wide-range biocatalytic diagnosis

Xiong, Chao; Li, Qian; Yang, Jiani; Cheng, Liang; Adeli, Mohsen; Luo, Xianglin; Xu, Xiaohui; He, Chao; Cheng, Chong

doi:10.1016/j.cej.2024.151881

Chemical Engineering Journal

2024

DOI: 10.1016/j.cej.2024.151881

|View full text |Cite

Covalent copper-organic frameworks with light-activable catalytic centers as smart artificial enzymes for highly sensitive and wide-range biocatalytic diagnosis

Chao Xiong,

Qian Li,

Jiani Yang

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

2025

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 62 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Room‐Temperature Single‐Phase Synthesis of Semiconducting Metal‐Covalent Organic Frameworks With Microenvironment‐Tuned Photocatalytic Efficiency

Wu,

Zhang,

Yin

et al. 2024

Small Methods

View full text Add to dashboard Cite

In order to improve the solubility of metallated monomers and product crystallinity, metal–covalent organic frameworks (MCOFs) are commonly prepared via high‐temperature sol‐vothermal synthesis. However, it hampers the direct extraction of crystallization evolution information. Exploring facile room‐temperature strategies for both synthesizing MCOFs and exploiting the crystallinity mechanism is extremely desired. Herein, by a novel single‐phase synthetic strategy, three MCOFs with different microstructure is rapidly prepared based on the Schiff base reaction between planarity‐tunable C3v monomers and metallated monomers at room temperature. Based on detailed time‐dependent experiments and theoretical calculations, it is found that there is a planarity‐tuned and competitive growth relationship between disordered structures and crystal nucleus for the first time. The high planarity of monomers boosts the formation of crystal nucleus and rapid growth, suppressing the forming of amorphous structures. In addition, the microenvironment effect on selective photocatalytic coupling of benzylamine (BA) is investigated. The strong donor‐acceptor (D‐A) MCOF exhibits efficient photocatalytic activity with a high conversion rate of 99% and high selectivity of 99% in 5 h under the 520 nm light irradiation. This work opens a new pathway to scalable and efficient synthesis of highly crystalline MCOFs.

show abstract

Room‐Temperature Single‐Phase Synthesis of Semiconducting Metal‐Covalent Organic Frameworks With Microenvironment‐Tuned Photocatalytic Efficiency

Wu,

Zhang,

Yin

et al. 2024

Small Methods

View full text Add to dashboard Cite

show abstract

Preparation of POMOF/g-C3N4 peroxidase-like artificial enzyme and its colorimetric sensing towards H2O2 and glutathione

Liu,

Liang,

Yang

et al. 2025

Inorganic Chemistry Communications

View full text Add to dashboard Cite

A dual-signal sensing platform based on single atomic iron-nitrogen-carbon nanozyme for the detection of neurodegenerative disease-related bioactive molecules acetylcholinesterase and dopamine

Han,

Zhou,

et al. 2025

Sensors and Actuators B: Chemical

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Covalent copper-organic frameworks with light-activable catalytic centers as smart artificial enzymes for highly sensitive and wide-range biocatalytic diagnosis

Cited by 3 publications

References 62 publications

Room‐Temperature Single‐Phase Synthesis of Semiconducting Metal‐Covalent Organic Frameworks With Microenvironment‐Tuned Photocatalytic Efficiency

Room‐Temperature Single‐Phase Synthesis of Semiconducting Metal‐Covalent Organic Frameworks With Microenvironment‐Tuned Photocatalytic Efficiency

Preparation of POMOF/g-C3N4 peroxidase-like artificial enzyme and its colorimetric sensing towards H2O2 and glutathione

A dual-signal sensing platform based on single atomic iron-nitrogen-carbon nanozyme for the detection of neurodegenerative disease-related bioactive molecules acetylcholinesterase and dopamine

Contact Info

Product

Resources

About