“…Benzo[ b ]selenophenes have attracted much attention because they are proved to act as organic semiconductors in organic light-emitting diodes and organic field-effect transistors. 10 Compared with existing methods to construct benzo[ b ]selenophene structure, 11 the notable features of the reaction are as follows: (1) it does not require any reactive functionalities, such as C–X, C–I + , C–B, or C–N 2 + ; (2) it does not require easily broken Se–Se or C(sp 3 )–Se bond; (3) it does not require harsh reaction conditions such as high temperature and the participation of acid; (4) it proceeds through the cleavage of inert C–H and stable C(sp 2 )–Se bonds.…”