Ferroelectricity, characterized by the reversible switching of spontaneous polarization (P s ) under external electric field, exists in polar crystalline materials without a spatial-inversion symmetry. On account of inherent P s , ferroelectric materials show intriguing physical properties including piezoelectricity, pyroelectricity, second-order optical nonlinearity, and electro-optic effect. Such functions of ferroelectric materials have been widely used for practical applications. Recently, hybrid perovskites are emerging as a promising ferroelectric family that enables the combination and/or coupling of ferroelectricity, photoexcitation, and semiconductor behaviors. Due to the polarization deterioration caused by leakage current of photoexcited carriers, however, it is still a challenge to accomplish practical applications of ferroelectric semiconductors in the photoelectric field. In this review, the recent progress of ferroelectric system of perovskite-type hybrids with different dimensions is summarized. Primarily, a brief description of crystallographic symmetry breaking which is a fundamental criterion to creating ferroelectricity, is illuminated. The combination and/or coupling of photoelectric properties with ferroelectric P s is then presented. Finally, the further development tendency and possible application outlooks of this ferroelectric material system are prospected.