2009
DOI: 10.1002/anie.200906552
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Cover Picture: Quadrannulene: A Nonclassical Fullerene Fragment (Angew. Chem. Int. Ed. 2/2010)

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“…These compounds are the only representatives of planar heteroannulated cyclooctatetraenes. It is shown that high molecular symmetry of hetero [8]circulenes and the extended specific p-conjugated chain are the main factors responsible for high stability of the crystal packing modes and the optical and magnetic properties of these compounds. These effects also determine numerous selection rules for electronic and vibrational transitions in UV-Vis, IR and Raman spectra.…”
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“…These compounds are the only representatives of planar heteroannulated cyclooctatetraenes. It is shown that high molecular symmetry of hetero [8]circulenes and the extended specific p-conjugated chain are the main factors responsible for high stability of the crystal packing modes and the optical and magnetic properties of these compounds. These effects also determine numerous selection rules for electronic and vibrational transitions in UV-Vis, IR and Raman spectra.…”
mentioning
confidence: 99%
“…The present review highlights recent advances in experimental and theoretical chemistry dealing with investigation of the electronic structures and physicochemical properties of hetero [8]circulenes. These compounds are the only representatives of planar heteroannulated cyclooctatetraenes.…”
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confidence: 99%
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