In this work, we perform a detailed study of the τ − → π − π 0 γν decay process within the resonance chiral theory. We pay special attention to the triple-product T-odd asymmetry in the τ − → π − π 0 γν process. The minimal resonance chiral Lagrangian and the odd-intrinsic parity resonance operators are simultaneously included to calculate the decay amplitudes. Various invariant-mass distributions in the π − π 0 , π − γ and π 0 γ systems are studied and they reveal different resonance dynamics. We further predict the intriguing nonzero Todd asymmetry distributions, which may provide useful guidelines for future experimental measurements conducted at the Belle-II and super tau-charm facilities.