2024
DOI: 10.1002/cphc.202400543
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CPL of Mellein and Related Natural Compounds: Analysis of the ESIPT Phenomenon

Giuseppe Mazzeo,
Marco Fusè,
Julien Bloino
et al.

Abstract: (R)‐(‐)‐Mellein, (3R,4R)‐4‐hydroxymellein and (3R,4S)‐4‐hydroxymellein obtained from fungi, i.e. from Diplodia globulosa, were investigated as a class of natural products presenting ESIPT (excited state intramolecular proton transfer) phenomenon, through fluorescence and CPL (circularly polarized luminescence). The study was preceded by the assessment of the absolute configuration through ECD and VCD (electronic and vibrational circular dichroism) spectroscopies in addition to NMR spectra. It is found that ESI… Show more

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