2015
DOI: 10.1016/j.jallcom.2014.12.188
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Cr enhanced ferromagnetism in La0.5Ba0.5CoO3 due to possible double-exchange interaction

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Cited by 6 publications
(1 citation statement)
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“…A comparison with the reference spectra reveals that the primary Cr valence in both geometries is from Cr 2+ , while the shoulder feature in the top bilayer can be associated with Cr 3+ . The mixed-valence Cr 2+ and Cr 3+ in the top sample critically changes the magnetic interactions to favor ferromagnetic ordering through a Cr 2+ -Cr 3+ double exchange (30)(31)(32). Complementary to this, the absence of any Cr 3+ contribution in the bottom bilayer suggests a weaker ferromagnetic ordering, representing a critical difference between the two interfaces.…”
Section: Spectroscopic Probing For the Origin Of Interface Asymmetrymentioning
confidence: 93%
“…A comparison with the reference spectra reveals that the primary Cr valence in both geometries is from Cr 2+ , while the shoulder feature in the top bilayer can be associated with Cr 3+ . The mixed-valence Cr 2+ and Cr 3+ in the top sample critically changes the magnetic interactions to favor ferromagnetic ordering through a Cr 2+ -Cr 3+ double exchange (30)(31)(32). Complementary to this, the absence of any Cr 3+ contribution in the bottom bilayer suggests a weaker ferromagnetic ordering, representing a critical difference between the two interfaces.…”
Section: Spectroscopic Probing For the Origin Of Interface Asymmetrymentioning
confidence: 93%