An experiment was conducted to investigate the role of weld residual stress on stress corrosion cracking in welded carbon steel plates prototypic to those used for nuclear waste storage tanks. Carbon steel specimen plates were butt-joined with Gas Metal Arc Welding technique. Initial cracks (seed cracks) were machined across the weld and in the heat affected zone. These specimen plates were then submerged in a simulated high level radioactive waste chemistry environment. Stress corrosion cracking occurred in the aswelded plate but not in the stress-relieved duplicate. A detailed finite element analysis to simulate exactly the welding process was carried out, and the resulting temperature history was used to calculate the residual stress distribution in the plate for characterizing the observed stress corrosion cracking. It was shown that the cracking can be predicted for the through-thickness cracks perpendicular to the weld by comparing the experimental K ISCC to the calculated stress intensity factors due to the welding residual stress. The predicted crack lengths agree reasonably well with the test data. The final crack lengths appear to be dependent on the details of welding and the sequence of machining the seed cracks, consistent with the prediction.Keywords: GMAW, SCC, IGSCC, finite element analysis, welding simulation, residual stress, stress intensity factor, K ISCC .
INTRODUCTIONA285 carbon steel has been used to construct high level nuclear waste storage tanks. The steel plates were joined by Gas Metal Arc Welding (GMAW). It was found that the weldments are susceptible to intergranular stress corrosion cracking (IGSCC) in a region spanning the weld. The cause of cracking is attributed to nitrate stress corrosion cracking driven by the residual stress due to the welding of the large plates during construction. The stress corrosion cracking (SCC) has occurred in or near the welds of some storage tanks containing a corrosive chemistry, and that were non-stress relieved. This degradation phenomenon has been investigated by experimentation to provide information on crack formation in welded plates, prototypic to tank construction.The SCC experiment used two 30.5 cm x 30.5 cm (1 ft. x 1 ft.) welded plates following the carbon steel tank fabrication procedure used in 1950's. The corners of the plates were constrained during welding to simulate the large plate welding in the tank construction. Seed cracks were fabricated across and parallel to the weld using electric discharge machining (EDM). One of the plates was stress relieved and the other was as-welded. These test specimens were submerged in 5 molar (5M) sodium nitrate (NaNO 3 ) solution at about 90 °C up to 10 weeks. Periodic inspections were performed. It is found that the as-welded plate exhibited cracking within two weeks of exposure, and the stress-relieved plate remained intact. This test has successfully demonstrated that the SCC can indeed occur in non-stress relieved A285 tanks, and the stress relief procedure that was implemented for l...