If there is no protective equipment in martial art single practice, it is very easy to be injured, so protective equipment in martial arts has been paid more and more attention. The protective effect of Wushu Sanda protective gear is related to the safety of every Wushu Sanda practitioner. The purpose of this paper is to study crystalline nanooptical materials and Wushu Sanda protective gear and propose the idea of using more crystalline nanooptical materials in the manufacture and use of Wushu Sanda protective gear. This paper mainly introduces the related content of crystalline nanooptical materials, martial art single-leg kick, and martial art single-leg protective gear and conducts experiments on crystalline nanooptical materials and martial art single-leg protective gear based on crystalline nanooptical materials. The experimental results show that the protective effect of protective equipment based on crystalline nanooptical materials can play a greater role than traditional protective equipment. In the experiments in this paper, the martial art single-leg kicking protective gear based on crystalline nanooptical materials has at least a 10% improvement in protective effect.