We investigate experimentally the quenching of a liquid pancake, obtained through the impact of a water drop on a cold solid substrate (0 to −60• C). We show that, below a certain substrate temperature, fractures appear on the frozen pancake and the crack patterns change from a 2D fragmentation regime to a hierarchical fracture regime as the thermal shock is stronger. The different regimes are discussed and the transition temperatures are estimated through classical fracture scaling arguments. Finally, a phase diagram presents how these regimes can be controlled by the drop impact parameters.When molten glass drips into cold water, the outside cools -and shrinks -faster than the inside, creating pentup tension in the so-called Prince Rupert's drop, known since before 1625 to have very striking mechanical properties [1,2]. Indeed, while the drop's head stays impervious to even the strongest blows, flick the tail and the whole drop shatters in a myriad of small pieces, in less than a millisecond. In the same way, fragmentation is in fact present in many physical processes, from jet atomization to bubble bursting in fluids [3][4][5], from spaghetti breaking [6] to popping balloons [7] or broken windows in solids [8,9]. It is related to diverse applications such as comminution [10], shell case bursting [11], ash generation during eruption [12,13] or meteoric cratering [14] for instance.Fragmentation is thus a sudden process, where the considered domain mainly divides in one go, with a very fast cracks front propagation. At least as ubiquitous, there exists a complete different crack morphology where space-dividing pattern shows a strong hierarchy of slower fractures [15]. Fractures develop successively, and each new fracture joins older fractures at a typical angle close to ninety degrees [16,17]. Such patterns are usually observed when the shrinking of a material layer is frustrated by its deposition on a non shrinking substrate, such as drying-induced cracks in mud [18,19] In this paper, we investigate experimentally the quenching of a liquid pancake that is obtained through the impact of a water drop on a very cold solid substrate. We show for the first time that, as a function of the substrate temperature, the crack patterns produced by the thermal shock, change from a 2D fragmentation regime to a hierarchical fracture regime, and the transition temperatures are estimated and discussed.The experimental setup consists in dropping a drop of water, with a diameter D 0 = 3.9 mm, on a steel substrate, so as to form a liquid pancake of radius R and typical thickness h 0 (see Fig. 1). Under this simplified geometry h 0 can be estimated by balancing the volume of the drop with that of the cylindrical pancake2 . The impact velocity is close to the free fall one : U 0 ∼ √ gH where H is the falling height. Throughout most of the paper, falling height will be kept constant at H = 36 cm. Subsequent pancake radius is : R 8 mm, from which pancake thickness can be deduced : h 0 150µm. The temperature of the substrate T s is typ...