The oxidation of isopropyl, benzyl, and n butyl alcohols to the corresponding aldehydes with tetramethylammonium fluorochromate was studied by spectrophotometry in acetonitrile solutions in the presence of p toluenesulfonic acid. The reaction kinetics was studied under pseudo first order conditions with respect to the oxidizing agent. The Michaelis-Menten kinetics with respect to the substrate was observed, indicating the quasi equilibrium formation of an oxidizing agent-alcohol complex. The formation constants and the rates of dispropor tionation of the complexes were determined. The temperature dependences of the reaction rates were studied, and the activation parameters were computed. A reaction scheme consistent with the observed results was proposed.