2023
DOI: 10.1002/asia.202300727
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Creation of a Highly Active Small Cu‐Based Catalyst Derived from Copper Aluminium Layered Double Hydroxide Supported on α‐Al2O3 for Acceptorless Alcohol Dehydrogenation

Febi Yusniyanti,
Takayoshi Hara,
Kohei Makishima
et al.

Abstract: A highly dispersed carbonate‐intercalated Cu2+‐Al3+ layered double hydroxide (CuAl LDH) was created on an unreactive α‐Al2O3 surface (CuAl LDH@α‐Al2O3) via a simple coprecipitation method of Cu2+ and Al3+ under alkaline conditions in the presence of α‐Al2O3. A highly reducible CuO nanoparticles was generated, accompanied by the formation of CuAl2O4 on the surface of α‐Al2O3 (CuAlO@α‐Al2O3) after calcination at 1073 K in air, as confirmed by powder X‐ray diffraction (XRD) and Cu K‐edge X‐ray absorption near edg… Show more

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