Electric vehicles (EVs) are important elements in the global strategy to tackle climate change; however, research often fails to sufficiently identify the range of barriers which affect their adoption. Taking Saudi Arabia as a case study, this paper analyses responses from 698 potential drivers in order to identify and rank the infrastructure, performance, financial, social, and policy barriers to EV adoption in a major oil-producing nation with a hot climate and a desert terrain. According to this study’s findings, the most important barriers in this context are the lack of charging infrastructure and the additional load placed on the national grid, while others include the safety and effectiveness of batteries at high temperatures, and the ability of EVs to perform in desert conditions. Common themes also include concerns that EVs may damage Saudi’s oil-based economy, cost of purchase and maintenance, low resale value, and the absence of awareness about EVs. The study concludes that EV manufacturers must demonstrate that their vehicles are suitable for the Saudi climate. Governments should also provide subsidies, or other incentives, to promote adoption of EVs as the study also found that variations in the cost of different EV models in Saudi Arabia, for example, the Tesla Model 3, is up to 40% more expensive to own than a Toyota Camry, mean that owning EVs can cost significantly more than small sized internal combustion engine-based vehicles (ICEVs). This paper identifies and ranks the barriers to EV ownership in a desert nation which is a leading petroleum producer and compares the relative costs of EVs and ICEVs in the country. As such, it has immediate relevance in countries with similar economic, geographic, and climatic conditions.