Chaos synchronization plays vital functions in the fields of optical chaos secure communication. The synchronization performance can be significantly degraded by parameter mismatches between the chaotic transmitter and receiver. In this paper, the Deep-Logistical Mapping Echo State Network (D-LMESN) is proposed to enhance the performance of chaos synchronization. The network is upgraded by using an improved logical mapping algorithm and a deep reserve pool structure with phase space reconstruction. Results show that D-LMESN exhibits better performance in the prediction of chaotic time series, thanks to the adaptive parameter adjustment, which increases the ability to capture the dynamic characteristics of complex systems. Compared with ESN, the mean square error of this model is reduced by 55% and 72%, respectively, in chaotic laser simulation and actual data experiments. This provides a new possibility, to our knowledge, for the development of chaotic secure communication.