In the Hamburg cold atom experiment with orbital states in an optical lattice, s-and p-orbital atomic states hybridize between neighboring sites. In this work we show how this alternation of sites hosting s-and p-orbital states gives rise to a plethora of different magnetic phases, quantum and classical. We focus on phases whose properties derive from frustration originating from a competition between nearest and next nearest neighboring exchange interactions. The physics of the Mott insulating phase with unit filling is described by an effective spin-1/2 Hamiltonian showing great similarities with the J 1 -J 2 model. Based on the knowledge of the J 1 -J 2 model, supported by numerical simulations, we discuss the possibility of a quantum spin liquid phase in the present optical lattice system. In the superfluid regime we consider the parameter regime where the s-orbital states can be adiabatically eliminated to give an effective model for the p-orbital atoms. At the mean-field level we derive a generalized classical XY model, and show that it may support maximum frustration. When quantum fluctuations can be disregarded, the ground state should be a spin glass. Figure 5. The energy of the ground state of the effective Hamiltonian for the Mott insulating phase (9). The energy is found for zero field h=0, and for = = J J J 0.9 X Y Z 1 1 1 , and as a function of J J Z Z 2 1 . The plot shows that an energy plateau is formed around = J J 0.5 Z Z 2 1 indicating the possibility that a there is an intermediate phase in between the Néel and striped phases.we see four distinct phases, the ferromagnetic phase (green), the Néel phase (white), the striped phase (dark pink), and the disordered phase (pink). In this (classical) limit all phase transitions are first first order. As we consider non-zero couplings = J J X Y 1 1 a fifth mean-field phase appears (light green/pink), this phase grows with increasing couplings = J J X Y 1 1 , and all PTs except for the one between the Néel phase and the ferromagnet phase, and the Néel and the new phase, appear to be second order. The new phase survives also for zero field, J Z =0, provided that = J J X Y 1 1 is large enough. At this mean-field level, the properties of the intermediate fifth phase is unknown. The dispersed dots are numerical errors for which the simulations are not capable of finding the true ground state.