Cross-coupling Reaction of Aryl(triethyl)silanes with Aryl Chlorides: An Easy Access to Oligothiophenes

The Versatile and Strategic O-Carbamate Directed Metalation Group in the Synthesis of Aromatic Molecules: An Update

“…The product heteroaryl/naphthyl silanes shown in Schemes – and Table have further utility because the silane groups can now be replaced by halogens, protodesilylated, , borylated, carboxylated, or used as a site for further CC. − …”

Copper-promoted difunctionalization of unactivated alkenes with silanes

“…3 d,f , i ,4 In addition, silicon-containing compounds are useful intermediates in many organic transformations due to their low-toxicity and easy-to-handle properties. 5 As a consequence, a variety of synthesis strategies have been utilized to construct organosilicon compounds. Traditional methods for the synthesis of silicon-containing compounds usually use trimethylsilyl chloride (TMSCl) and trimethylsilyl trifluoromethanesulfonate (TMSOTf) as electrophilic silylation reagents, 6 which require pyrophoric lithium reagents to prefunctionalize the reaction partners or the use of sufficient base to neutralize the acid produced in the reaction.…”